Nice work!
To use the Accent defined in the application resources, I deleted accent defined in Metro.xaml. The remaining problem is the Accent of Inactive Window.
"WPF.MDI\\Themes\\Metro.xaml", commented out line 10-12:
<!-- Deleted to use Accent defined in App.xaml -->
<!--
<Color x:Key="AccentColor">#CC161717</Color>
<Color x:Key="AccentBaseColor">#CC161717</Color>
<Color x:Key="AccentColor2">#868686</Color>
-->
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